Nickel-Catalyzed Stereoselective Arylboration of Unactivated Alkenes
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Date
2019-01-10
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Abstract
A Ni-catalyzed method for arylboration is disclosed. The method allows for highly stereoselective arylboration of unactivated alkenes. The reactions utilize a simple Ni-catalyst and work with a broad range of alkenes and aryl bromides. The products represent useful intermediates for chemical synthesis due to the versatility of the C−B bond. Preliminary mechanistic details of the method are also disclosed.
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Logan, K. M., et al. "Nickel-Catalyzed Stereoselective Arylboration of Unactivated Alkenes." Journal of the American Chemical Society, vol. 140, no. 1, pp. 159-162, 2019-01-10, https://doi.org/10.1021/jacs.7b12160.
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Journal of the American Chemical Society