Copper-Catalyzed Heteroarylboration of 1,3-Dienes with 3-Bromopyridines: A cine Substitution

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A method for the heteroarylboration of 1,3-dienes is presented. The process involves an unusual cine substitution of 3-bromopyridine derivatives to deliver highly functionalized heterocyclic products. Mechanistic studies are included that clarify the details of this unusual process.

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Smith, K B, et al. "Copper-Catalyzed Heteroarylboration of 1,3-Dienes with 3-Bromopyridines: A cine Substitution." Angewandte Chemie, vol. 57, no. 21, pp. 6146-6149, 2018-04-26, https://doi.org/10.1002/ange.201801139.

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Angewandte Chemie

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