Electrode-adsorption activates trans-[Cr(cyclam)Cl2]+ for electrocatalytic nitrate reduction

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dc.contributor.authorBraley, Sarah E.
dc.contributor.authorAshley, Daniel C.
dc.contributor.authorJakubikova, Elena
dc.contributor.authorSmith, Jeremy M.
dc.date.accessioned2025-02-20T15:52:09Z
dc.date.available2025-02-20T15:52:09Z
dc.date.issued2020-01-01
dc.descriptionThis record is for a(n) postprint of an article published in Chemical Communications on 2020-01-01; the version of record is available at https://doi.org/10.1039/c9cc08550e.
dc.description.abstractCyclic voltammetry reveals that aqueous trans-[Cr(cyclam)Cl$_2$]$^+$ is reversibly reduced at a mercury electrode, with a small prewave suggesting an adsorptive interaction between the complex and electrode surface. A catalytic current is observed in the presence of excess nitrate, with the onset potential for catalysis at the prewave. Nitrate is electrocatalytically reduced to nitrite, with preliminary mechanistic investigations implicating a chromium oxo intermediate.
dc.description.versionpostprint
dc.identifier.citationBraley, Sarah E., et al. "Electrode-adsorption activates trans-[Cr(cyclam)Cl2]+ for electrocatalytic nitrate reduction." Chemical Communications, 2020-01-01, https://doi.org/10.1039/c9cc08550e.
dc.identifier.otherBRITE 6871
dc.identifier.urihttps://hdl.handle.net/2022/32638
dc.language.isoen
dc.relation.isversionofhttps://doi.org/10.1039/c9cc08550e
dc.relation.journalChemical Communications
dc.rightsThis work may be protected by copyright unless otherwise stated.
dc.titleElectrode-adsorption activates trans-[Cr(cyclam)Cl2]+ for electrocatalytic nitrate reduction

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