Thioallenoates in Catalytic Enantioselective [2+2]-Cycloadditions with Unactivated Alkenes
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Abstract
The application of thioallenoates to catalytic enantioselective [2+2]-cycloadditions with unactivated alkenes is reported.In many cases, the thioallenoates examined exhibit superior reactivity and selectivity compared to the alkoxy analogs generally used in these cycloadditions.
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Keywords
Cycloaddition, Enantioselective, Lewis-Acid, Allenes, Cyclobutane
Citation
Conner, Michael L., et al. "Thioallenoates in Catalytic Enantioselective [2+2]-Cycloadditions with Unactivated Alkenes." Tetrahedron, vol. 75, no. 24, 2019-04-25.
Journal
Tetrahedron