Cyanide Ligand Assembly by Carbon Atom Transfer to an Iron Nitride

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dc.contributor.authorMartinez, Jorge L.
dc.contributor.authorLin, Hsiu-Jung
dc.contributor.authorLee, Wei-Tsung
dc.contributor.authorPink, Maren
dc.contributor.authorChen, Chun Hsing
dc.contributor.authorGao, Xinfeng
dc.contributor.authorDickie, Diane
dc.contributor.authorSmith, Jeremy Michael
dc.date.accessioned2025-02-20T16:33:17Z
dc.date.available2025-02-20T16:33:17Z
dc.date.issued2017-09-21
dc.descriptionThis record is for a(n) postprint of an article published in J. Am. Chem. Soc. on 2017-09-21; the version of record is available at https://doi.org/10.1021/jacs.7b08704.
dc.description.abstractThe new iron(IV) nitride complex PhB($^i$Pr$_2$Im)$_3$Fe≡N reacts with 2 equiv of bis(diisopropylamino)cyclopropenylidene (BAC) to provide PhB($^i$Pr$_2$Im)$_3$Fe(CN)(N2)(BAC). This unusual example of a four-electron reaction involves carbon atom transfer from BAC to create a cyanide ligand along with the alkyne $^i$Pr$_2$N–C≡C–N$^i$Pr$_2$. The iron complex is in equilibrium with an N$_2$-free species. Further reaction with CO leads to formation of a CO analogue, which can be independently prepared using NaCN as the cyanide source, while reaction with B(C$_6$F$_5$)$_3$ provides the cyanoborane derivative.
dc.description.versionpostprint
dc.identifier.citationMartinez, Jorge L., et al. "Cyanide Ligand Assembly by Carbon Atom Transfer to an Iron Nitride." J. Am. Chem. Soc., vol. 139, no. 40, 2017-9-21, https://doi.org/10.1021/jacs.7b08704.
dc.identifier.issn1520-5126
dc.identifier.otherBRITE 1322
dc.identifier.urihttps://hdl.handle.net/2022/33028
dc.language.isoen
dc.relation.isversionofhttps://doi.org/10.1021/jacs.7b08704
dc.relation.journalJ. Am. Chem. Soc.
dc.titleCyanide Ligand Assembly by Carbon Atom Transfer to an Iron Nitride

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