Cyanide Ligand Assembly by Carbon Atom Transfer to an Iron Nitride

Simple item page
dc.contributor.authorMartinez, Jorge L.
dc.contributor.authorLin, Hsiu-Jung
dc.contributor.authorLee, Wei-Tsung
dc.contributor.authorPink, Maren
dc.contributor.authorChen, Chun Hsing
dc.contributor.authorGao, Xinfeng
dc.contributor.authorDickie, Diane
dc.contributor.authorSmith, Jeremy Michael
dc.date.accessioned2025-02-20T16:33:17Z
dc.date.available2025-02-20T16:33:17Z
dc.date.issued2017-09-21
dc.descriptionThis record is for a(n) postprint of an article published in J. Am. Chem. Soc. on 2017-09-21; the version of record is available at https://doi.org/10.1021/jacs.7b08704.
dc.description.abstractThe new iron(IV) nitride complex PhB($^i$Pr$_2$Im)$_3$Fe≡N reacts with 2 equiv of bis(diisopropylamino)cyclopropenylidene (BAC) to provide PhB($^i$Pr$_2$Im)$_3$Fe(CN)(N2)(BAC). This unusual example of a four-electron reaction involves carbon atom transfer from BAC to create a cyanide ligand along with the alkyne $^i$Pr$_2$N–C≡C–N$^i$Pr$_2$. The iron complex is in equilibrium with an N$_2$-free species. Further reaction with CO leads to formation of a CO analogue, which can be independently prepared using NaCN as the cyanide source, while reaction with B(C$_6$F$_5$)$_3$ provides the cyanoborane derivative.
dc.description.versionpostprint
dc.identifier.citationMartinez, Jorge L., et al. "Cyanide Ligand Assembly by Carbon Atom Transfer to an Iron Nitride." J. Am. Chem. Soc., vol. 139, no. 40, 2017-9-21, https://doi.org/10.1021/jacs.7b08704.
dc.identifier.issn1520-5126
dc.identifier.otherBRITE 1322
dc.identifier.urihttps://hdl.handle.net/2022/33028
dc.language.isoen
dc.relation.isversionofhttps://doi.org/10.1021/jacs.7b08704
dc.relation.journalJ. Am. Chem. Soc.
dc.rightsThis work may be protected by copyright unless otherwise stated.
dc.titleCyanide Ligand Assembly by Carbon Atom Transfer to an Iron Nitride

Files

Original bundle

Now showing 1 - 1 of 1
Thumbnail Image
Name:
1322_Cyanide-Ligand-Assembly.pdf
Size:
622.34 KB
Format:
Adobe Portable Document Format
Download

Collections

Faculty Open Access Articles
Can’t use the file because of accessibility barriers? Contact us