Near-infrared 2Eg → 4A2g luminescence from a molecular bis-(tris(carbene)borate)manganese(IV) complex

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dc.contributor.authorBaslon, Valerie
dc.contributor.authorHarris, Joseph P.
dc.contributor.authorReber, Christian
dc.contributor.authorColmer, Hannah
dc.contributor.authorJackson, Timothy A.
dc.contributor.authorForshaw, Adam P.
dc.contributor.authorSmith, Jeremy M.
dc.contributor.authorKinney, R. Adam
dc.contributor.authorTelser, Joshua
dc.date.accessioned2025-02-20T16:56:55Z
dc.date.available2025-02-20T16:56:55Z
dc.date.issued2017-02-08
dc.description.abstractThe molecular bis-(tris(carbene)borate) manganese(IV) complex [{PhB(MeIm)$_3$}$_2$Mn](OTf)$_2$ shows $^2$E$_g$ → $^4$A$_{2g}$ luminescence at 828 nm in the solid state at 85 K; this wavelength is longer by approximately 100 nm than the wavelengths typically observed for manganese(IV) and chromium(III) doped solids and for molecular chromium(III) complexes. Weak luminescence is also observed from a LMCT excited state with an absorption maximum at 500 nm. This represents the first molecular manganese(IV) compound for which luminescence has been reported.
dc.identifier.citationBaslon, Valerie, et al. "Near-infrared 2Eg → 4A2g luminescence from a molecular bis-(tris(carbene)borate)manganese(IV) complex." Can. J. Chem., vol. 95, 2017-2-8, https://doi.org/10.1139/cjc-2016-0607.
dc.identifier.issn1480-3291
dc.identifier.otherBRITE 1325
dc.identifier.urihttps://hdl.handle.net/2022/32943
dc.language.isoen
dc.relation.isversionofhttps://doi.org/10.1139/cjc-2016-0607
dc.relation.isversionofhttps://tspace.library.utoronto.ca/handle/1807/75856
dc.relation.journalCan. J. Chem.
dc.titleNear-infrared 2Eg → 4A2g luminescence from a molecular bis-(tris(carbene)borate)manganese(IV) complex

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