Catalyst-Controlled 1,2- and 1,1-Arylboration of α-Alkyl Alkenyl Arenes

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dc.contributor.authorBergmann, Allison M.
dc.contributor.authorDorn, Stanna K.
dc.contributor.authorSmith, Kevin B.
dc.contributor.authorLogan, Kaitlyn M.
dc.contributor.authorBrown, Michael Kevin
dc.date.accessioned2025-02-20T16:19:32Z
dc.date.available2025-02-20T16:19:32Z
dc.date.issued2019-01-19
dc.description.abstractTwo methods are reported for the 1,2‐ and 1,1‐arylboration of α‐methyl vinyl arenes. In the case of 1,2‐arylboration, the formation of a quaternary center occurred through a rare cross‐coupling reaction of a tertiary organometallic complex. 1,1‐Arylboration was enabled by catalyst optimization and occurred through a β‐hydride elimination/reinsertion cascade. Enantioselective variants of both processes are presented as well as mechanistic investigations.
dc.identifier.citationBergmann, Allison M., et al. "Catalyst-Controlled 1,2- and 1,1-Arylboration of α-Alkyl Alkenyl Arenes." Angewandte Chemie, vol. 58, no. 6, 2019-01-19, https://doi.org/10.1002/anie.201812533.
dc.identifier.issn1433-7851
dc.identifier.otherBRITE 4675
dc.identifier.urihttps://hdl.handle.net/2022/31409
dc.language.isoen
dc.relation.isversionofhttps://doi.org/10.1002/anie.201812533
dc.relation.isversionofhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC6823597
dc.relation.journalAngewandte Chemie
dc.titleCatalyst-Controlled 1,2- and 1,1-Arylboration of α-Alkyl Alkenyl Arenes

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