Nickel-Catalyzed Arylboration of Alkenylarenes: Synthesis of Boron-Substituted Quaternary Carbons and Regiodivergent Reactions

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https://doi.org/10.1002/anie.201904861
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6663602

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2019-06-28

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https://hdl.handle.net/2022/31412

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A method for the construction of boron‐substituted quaternary carbons or diarylquaternary carbons by arylboration of highly substituted alkenylarenes is presented. A wide range of alkenes and arylbromides can participate in this reaction thus allowing for a diverse assortment of products to be prepared. In addition, a solvent dependent regiodivergent arylboration of 1,2‐disubstituted alkenylarenes is presented, thus greatly increasing the scope of products that can be accessed.

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Chen, Liang-An, et al. "Nickel-Catalyzed Arylboration of Alkenylarenes: Synthesis of Boron-Substituted Quaternary Carbons and Regiodivergent Reactions." Angewandte Chemie, vol. 58, no. 32, 2019-06-28, https://doi.org/10.1002/anie.201904861.

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Angewandte Chemie

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Faculty Open Access Articles